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GPx는 다양한 종류의 organic peroxide를 기질로 이용하지만 환원시에는 phospholipid hydroperoxide GPx와 Plasma GPx를 제외하고 대부분의 GPx가 GSH를 기질로 이용한다 phospholipid-hydroperoxide GPx는 유일하게 세포막의 phospholipid와 cholesterol에 대해 강한 활성을 가지고 있는 효소이다