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Therefore, the sulfuranyl free radical on the S-atom of Met35 could be formed by molecular oxygen interaction with the S-atom of Met35, leading to an electron transfer to oxygen from the S-atom resulting in the reduction of oxygen to superoxide free radical and the one-electron oxidation of the S-atom to the sulfuranyl free radical and/or ii ) Cu 2+ weakly bound to the S-atom of Met35 conceivably would lead to a one-electron reduction of Cu 2+ and oxidation of the S-atom to the sulfuranyl free radical as discussed above