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It is worth noting that glutathione disulfide is structurally close to both the metal(II)-bis-glutathionato conjugates (GS-M-SG) and to the lanthionine-bound glutathione thioether dimer (G-S-G) produced by nucleophilic attack of the thiolate group of glutathione to the electrophilic carbon of dehydro-alanine (acrylate) glutathione, as shown in Scheme 10