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Structure and catalytic mechanism of α-ketoglutarate dehydrogenase α -Ketoglutarate dehydrogenase (KGDH) is a large multi-sub-unit enzyme complex composed of multiple copies of three sub-units: E1 ( α -ketoacid decarboxylase), E2 (dihydrolipoyl transacetylase) and E3 (dihydrolipoamide dehydrogenase) (Scheme 2)
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